2nd Inventors' Olympiad - GENIUS 2000 Budapest, Virtual Exhibition

Registry number: C-214 Category: C Country: Hungary
The recycling of mud containing heavy metals
The invention
  • The problem to be solved:
    The different mud
    that remain after leather processing and galvanisation technologies are hazardous waste. The invention offers solution for the extraction of metals and the utilisation of the remaining mud with an environment friendly technology. The results are given back to the industry and agriculture for reuse.
  • Definition:
    The mud containing heavy metals are treated in two phases after the filtering. The filtrate with the help of electrolysis and osmosis, after the parameters are adjusted, is given back to the factories for reuse. The heavy metals are cleared off from the dry material with washing in pulsating electric field and with pH adjustment. The mud containing no metal is utilised as humus, while the washing liquid is handled together with the filtrate.
  • Presentation:
    The pH of the chromic mud is adjusted to 1.5 with sulphuric acid, and under constant stirring the temperature is kept at 50 – 80 C
    ° for 1.5 hours, while flocculating agent is added as well. Afterwards the suspension is filtered, and then after electroflotation (which is microelement filtration) it is dehydrated through osmosis. After the concentration process the chemical adjustment will follow (tan liquor H2SO4+Cr2 (SO4)3 and the recycled tan liquor is returned to the leather industry. The water produced during the concentration after the osmosis will be utilised in the washing process. The residual dry material will be washed after homogenisation at pH 2 – 5, in a pulsating electric field, at a 0 –80 V/cm field intensity in every 10 –20 seconds. The washing process is continued until the chromic content of the dry material decrease under the permissible 1000-mg/kg value. The washing liquid is also concentrated by the help of osmosis, and the resulting solution, which contains chrome, will be adjusted at the same level that of the tan liquor and will be returned to the washing cycle. The cleaned dry material is mixed with humite, and straw and can be utilised in the agriculture as humus. In case the tan liquor cannot be returned into the leather processing technologies as it is, than from the concentrated chrome III solution chome alumen (KCr(SO4)2-12H2) is produced, that is neutralised with potassium carbonate, or potassium hydroxide added, and after evaporation, and cooling the chome alumen is filtered.

  • Application: Environmentand recycling.
  • Advantages:
    The protection of the environment. The reuse, recycling of hazardous wastes in an environment friendly way. The production of useful recycled materials from the waste for the industry and the agriculture. The recycling reduces the amount of the hazardous material input in waste management.
    Economic advantages.
  • Stage of development:
    Examined successful semi-plant experiment.
  • Documentation available: Yes; the experimental machine will be exhibited during the fair
The inventor(s)
  • Name(s): Zoltán SZABÓ Dr.
  • Self introduction:
    He borns on 26/05/1963 in Budapest, He is a chemist. He is member of MAFE since 1991. Inventions are mainly about the utilisation of heavy metal muds. Disabled pensioner, inventor with three children.
The protection
  • Form: Exhibition priority
  • Priority: 04/05/2000
  • Countries where it is force:
Business intention: Finding the consumer, the buyer, the investor or the initiator of the invention
Contact
  • Name: Chemical-Cerebrum Kft.
  • E-mail: zolko@matavnet.hu
  • Fax: +36 76 355 101
  • Address: